CO2 emissions are highly spatially heterogeneous, not least because fossil fuels are mainly used in the industrialized areas of the northern hemisphere. An international effort has led to the development of a worldwide network of several dozen stations measuring pCO2 and other gases and associated parameters (notably δ13C). The longest continuous record (since 1958) is at the Mauna Loa station in Hawaii, where pCO2 is measured by an infrared spectroscopy system.
Each pCO2 record is characterized by a more or less marked seasonality, depending on the natural seasonal cycle of plant growth. This seasonality is particularly wide (> 20 ppm for pCO2 and 1 ‰ for δ13C) for the high latitudes of the northern hemisphere characterized by large continental forests.
For the same latitude, pCO2 shows a much more marked high-frequency variability (of 20-30 ppm and 1 ‰ for δ13C) for sites on the continent compared with those over the ocean. These fluctuations illustrate the rapid dynamics associated with the terrestrial biosphere and air mass mixing over the continents.
In addition to the seasonal cycle and high frequencies, all stations show a common long-term trend, with an increase rate of around 1 to 2 ppm per year. Time tracking reveals systematic variations, with maxima and minima corresponding to certain years (e.g. + 3.4 ppm in 1998 and + 0.6 ppm in 1992). This interannual modulation affects all latitudes, but variations are more marked in the northern hemisphere.